Boating

Captain Joe of Patouche Charters operates a day sail around the BVI. www.patouche.com

Mystique are based in West End and their day sails tend to go west i.e. to Sandy Spit, Green Cay, Jost Van Dyke etc. Occasionally they go the Baths in Virgin Gorda but it takes two hours to sail there so not really the best idea as you have to drive west to sail east.
http://www.mystiquecharters.com/bvi-excursions-yacht-charters/index.php?id=13
http://www.mystiquecharters.com/bvi-excursions-yacht-charters/index.php?id=13

Kuralu goes out of West End and goes to Jost Van Dyke, Sandy Spit etc.
http://www.kuralu.com/kuralu.htm
http://www.kuralu.com/kuralu.htm

Self Drive boat rentals
If you would like to hire a self-drive boat with an option to hire with a captain.
www.islandtimeltd.com
If you would like to hire a self-drive boat with an option to hire with a captain.
www.islandtimeltd.com